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- W2094401034 abstract "Abstract The electronic structure of the two‐fold bridged [1],[1]disilamolybdenocenophane has been analyzed by means of density functional theory. As predicted, the relatively high charge at the metal center and, in particular, the highly strained geometry determine a noticeable reactivity towards unsaturated organic substrates. Thus, treatment with the nonpolar reagents 2‐butyne and azobenzene leads to side‐on coordination of the substrate to the metal center, whereas the reaction with polar tert ‐butylisonitrile gives a highly unusual structural motif in the form of an ansa ‐carbene." @default.
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- W2094401034 date "2010-03-01" @default.
- W2094401034 modified "2023-10-18" @default.
- W2094401034 title "Electronic Structure and Reactivity of a [1],[1]Disilamolybdenocenophane" @default.
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- W2094401034 doi "https://doi.org/10.1002/chem.200902883" @default.
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