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- W2094462811 abstract "The microwave spectrum of phenol, C 6 12 H 5 O 16 H, was measured in the frequency range from 15 to 30 Gc/sec. A majority of the spectral lines was found to be doublet, which was explained as the effect of internal rotation of the OH-group in a hindering potential of the form V =( V 2 /2)×(1-cos 2 x ). The barrier height, V 2 was determined to be 1100±100 cm -1 from the observed splittings. By the use of a rigid rotor model, the effective rotational constants were calculated to be A =5650.46 Mc/sec, B =2619.20 Mc/sec and C =1789.84 Mc/sec. From these values, the OH-bond in its equilibrium configuration was found to lie on the plane comprising the C 6 H 5 -group." @default.
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- W2094462811 date "1960-02-01" @default.
- W2094462811 modified "2023-09-24" @default.
- W2094462811 title "Potential Barrier of Phenol from its Microwave Spectrum" @default.
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- W2094462811 doi "https://doi.org/10.1143/jpsj.15.284" @default.
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