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- W2094472254 abstract "An attempt has been made to achieve thermoplastic behaviour in a chemically crosslinked elastomer by arranging that the crosslinks should undergo rapid exchange at high temperatures. Natural rubber was chemically modified to give pendent hydroxyl groups which were then used as crosslinking sites to form β-keto-ester or malonate crosslinks. The resultant vulcanisates showed high stress relaxation rates in the temperature range 120 to 160°C and some degree of remouldability at 180°C. The incursion of permanent crosslinking prevented quantitative correlation between stress relaxation rates and chemical exchange rates of the crosslinking systems." @default.
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- W2094472254 date "1973-01-01" @default.
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- W2094472254 title "Exchange reactions as a basis of thermopiastic behaviour in crosslinked polymers" @default.
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