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• W2094481370 abstract "High-valent niobium bis-alkylidene complexes have been structurally authenticated along with the first paramagnetic Nb(IV) alkylidene. The bis-alkylidene complexes presented in this work are thought to be generated via a redox process involving α-hydride elimination from a transient Nb(III) bis-alkyl complex. X-ray diffraction, DFT, and multinuclear NMR studies are consistent with these bis-alkylidenes having drastically different chemical environments." @default.
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• W2094481370 date "2007-10-31" @default.
• W2094481370 modified "2023-09-24" @default.
• W2094481370 title "Niobium Bis-alkylidene Complexes Prepared by a Multi-Electron Redox Process" @default.
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• W2094481370 doi "https://doi.org/10.1021/om7008233" @default.
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