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- W2094558630 abstract "Abstract Hindered rotation in alkyldithiocarbamates of the type RR′NC(= S)SR″ [R, R′, R″ = Me, Me, Et (1); PhCH2, Me, Et (2); PhCH2, H, Et (3); PhCH2, H, Me (4) and O(CH2CH2)2, Et (5)′ has been investigated using variable-temperature 1H NMR spectroscopy in CDCl3, C6D6, and DMSO-d6 solutions. Rotational parameters were calculated by the coalescence temperature method. Nitrogen substituent effects on the free energy of activation and on the equilibrium constant of unsymmetrical conformers at room temperature are discussed." @default.
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- W2094558630 date "2013-07-01" @default.
- W2094558630 modified "2023-09-23" @default.
- W2094558630 title "Hindered Rotation in Some Organic Dithiocarbamates" @default.
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- W2094558630 doi "https://doi.org/10.1080/10426507.2012.723653" @default.
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