Matches in SemOpenAlex for { <https://semopenalex.org/work/W2094561306> ?p ?o ?g. }
Showing items 1 to 67 of
67
with 100 items per page.
- W2094561306 endingPage "399" @default.
- W2094561306 startingPage "389" @default.
- W2094561306 abstract "Cis- and trans-buten-2-yl free radicals are shown to react with butene-2 cis (Bc) and D2S in the following metathetical steps: giving rise to butenes-1 (B1). The initial formations of butene-1,3 d1 and total butene-1 in D2SBc mixtures have been studied in the initial pressure range 20–200 torr for Bc, 0–41 torr for D2S and at 717–817 K. The main initiation and termination steps are shown to be: Assuming a rapid equilibrium between cis- and trans-C4H7⋅, ki ≃ 1015.5 exp(−85.5/RT) s−1 (RT in kcal mol−1) and kt ≃ 1013 mol−1 cm3 s−1, we get: k2c′ = 1.1 k2t′ = 1012.0 exp[(−9.25 ± 2)/RT] mol−1 cm3 s−1 and k2 + 1.5 k2′ ≃ 1012.1 exp[(−15.2 ± 2)/RT] mol−1 cm3 s−1. Isotopic effects relating to processes (2c′) + (2t′) and to (i′) have been evaluated." @default.
- W2094561306 created "2016-06-24" @default.
- W2094561306 creator A5064619962 @default.
- W2094561306 creator A5080560768 @default.
- W2094561306 date "1985-04-01" @default.
- W2094561306 modified "2023-10-12" @default.
- W2094561306 title "Reactivities ofcis- andtrans-buten-2-yl free radicals in presence of D2S. II. Absolute values of rate constants and isotopic effects" @default.
- W2094561306 cites W2017659682 @default.
- W2094561306 cites W2029103481 @default.
- W2094561306 cites W2095038836 @default.
- W2094561306 cites W2151981965 @default.
- W2094561306 cites W2621598440 @default.
- W2094561306 doi "https://doi.org/10.1002/kin.550170405" @default.
- W2094561306 hasPublicationYear "1985" @default.
- W2094561306 type Work @default.
- W2094561306 sameAs 2094561306 @default.
- W2094561306 citedByCount "4" @default.
- W2094561306 crossrefType "journal-article" @default.
- W2094561306 hasAuthorship W2094561306A5064619962 @default.
- W2094561306 hasAuthorship W2094561306A5080560768 @default.
- W2094561306 hasConcept C10710636 @default.
- W2094561306 hasConcept C113196181 @default.
- W2094561306 hasConcept C121332964 @default.
- W2094561306 hasConcept C139066938 @default.
- W2094561306 hasConcept C147789679 @default.
- W2094561306 hasConcept C148898269 @default.
- W2094561306 hasConcept C155647269 @default.
- W2094561306 hasConcept C178790620 @default.
- W2094561306 hasConcept C185592680 @default.
- W2094561306 hasConcept C30646810 @default.
- W2094561306 hasConcept C62520636 @default.
- W2094561306 hasConcept C93391505 @default.
- W2094561306 hasConcept C97355855 @default.
- W2094561306 hasConceptScore W2094561306C10710636 @default.
- W2094561306 hasConceptScore W2094561306C113196181 @default.
- W2094561306 hasConceptScore W2094561306C121332964 @default.
- W2094561306 hasConceptScore W2094561306C139066938 @default.
- W2094561306 hasConceptScore W2094561306C147789679 @default.
- W2094561306 hasConceptScore W2094561306C148898269 @default.
- W2094561306 hasConceptScore W2094561306C155647269 @default.
- W2094561306 hasConceptScore W2094561306C178790620 @default.
- W2094561306 hasConceptScore W2094561306C185592680 @default.
- W2094561306 hasConceptScore W2094561306C30646810 @default.
- W2094561306 hasConceptScore W2094561306C62520636 @default.
- W2094561306 hasConceptScore W2094561306C93391505 @default.
- W2094561306 hasConceptScore W2094561306C97355855 @default.
- W2094561306 hasIssue "4" @default.
- W2094561306 hasLocation W20945613061 @default.
- W2094561306 hasOpenAccess W2094561306 @default.
- W2094561306 hasPrimaryLocation W20945613061 @default.
- W2094561306 hasRelatedWork W1964249238 @default.
- W2094561306 hasRelatedWork W2000382468 @default.
- W2094561306 hasRelatedWork W2014007590 @default.
- W2094561306 hasRelatedWork W2061389065 @default.
- W2094561306 hasRelatedWork W2066185644 @default.
- W2094561306 hasRelatedWork W2076824375 @default.
- W2094561306 hasRelatedWork W2076966972 @default.
- W2094561306 hasRelatedWork W211066753 @default.
- W2094561306 hasRelatedWork W4241291716 @default.
- W2094561306 hasRelatedWork W62593916 @default.
- W2094561306 hasVolume "17" @default.
- W2094561306 isParatext "false" @default.
- W2094561306 isRetracted "false" @default.
- W2094561306 magId "2094561306" @default.
- W2094561306 workType "article" @default.