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• W2094612093 endingPage "2199" @default.
• W2094612093 startingPage "2192" @default.
• W2094612093 abstract "Previous studies have demonstrated that gas-phase H2S can immobilize certain redox-sensitive contaminants (e.g., Cr, U, Tc) in vadose zone environments. A key issue for effective and efficient delivery of H2S in these environments is the reactivity of the gas with indigenous iron oxides. To elucidate the factors that control the transport of H2S in the vadose zone, laboratory column experiments were conducted to identify reaction mechanisms and measure rates of H2S oxidation by iron oxide-coated sands using several carrier gas compositions (N2, air, and O2) and flow rates. Most experiments were conducted using ferrihydrite-coated sand. Additional studies were conducted with goethite- and hematite-coated sand and a natural sediment. Selective extractions were conducted at the end of each column experiment to determine the mass balance of the reaction products. XPS was used to confirm the presence of the reaction products. For column experiments in which ferrihydrite-coated sand was the substrate and N2 was the carrier gas, the major H2S oxidation products were FeS and elemental sulfur (mostly S80, represented as S0 for simplicity) at ratios that were consistent with the stoichiometry of the postulated reactions. When air or O2 were used as the carrier gas, S0 became the dominant reaction product along with FeS2 and smaller amounts of FeS, sulfate, and thiosulfate. A mathematical model of reactive transport was used to test the hypothesis that S0 forming on the iron oxide surfaces reduces access of H2S to the reactive surface. Several conceptual models were assessed in the context of the postulated reactions with the final model based on a linear surface poisoning model and fitted reaction rates. These results indicate that carrier gas selection is a critical consideration with significant tradeoffs for remediation objectives." @default.
• W2094612093 created "2016-06-24" @default.
• W2094612093 creator A5031539650 @default.
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• W2094612093 date "2003-04-12" @default.
• W2094612093 modified "2023-10-18" @default.
• W2094612093 title "Oxidation of H₂S by Iron Oxides in Unsaturated Conditions" @default.
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• W2094612093 doi "https://doi.org/10.1021/es020994o" @default.
• W2094612093 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12785525" @default.
• W2094612093 hasPublicationYear "2003" @default.
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