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- W2094644573 abstract "A new study has been made of the defect-induced one-phonon infrared absorption in a selected type-Ia diamond. Particular attention has been paid to the wavelength calibration of the spectrometer, and the frequency of a band near the one-phonon cut-off is put at 1331.8+or-0.5 cm-1 which is the same as the frequency ( omega R) of the first-order Raman line (1332.5+or-0.5 cm-1) within experimental error. Other related measurements on diamond and silicon are reviewed, and it is concluded that a peak occurs in the one-phonon density of states of diamond at, or very near, omega R, supporting the proposition that the maximum lattice frequency is greater than omega R. This is in agreement with previous speculations and calculations. Such a peak could explain the 'anomalous' band in the second-order Raman spectrum of diamond, although the fact that the frequency of the latter is slightly greater than 2 omega R remains to accounted for." @default.
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- W2094644573 date "1979-11-14" @default.
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- W2094644573 title "An infrared study of the maximum lattice frequency in diamond" @default.
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- W2094644573 doi "https://doi.org/10.1088/0022-3719/12/21/026" @default.
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