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- W2094654071 abstract "Treatment of steroid sapogenins with benzaldehyde and BF(3)·Et(2)O cleanly produces E-23(23')-benzylidenspirostanes in good yields in a reaction pathway which consists on an aldol reaction followed by a dehydration step. The obtained E-23(23')-benzylidenspirostanes can be easily converted to dinorcholanic lactones by treatment with CrO(3) in acetic acid. The synthetic sequence to dinorcholanic lactones is compatible with the presence of double bonds and carbonyl groups in the steroid framework." @default.
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- W2094654071 date "2012-06-01" @default.
- W2094654071 modified "2023-10-17" @default.
- W2094654071 title "BF3·Et2O-induced stereoselective aldol reaction with benzaldehyde, and steroid sapogenins and its application to a convenient synthesis of dinorcholanic lactones" @default.
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- W2094654071 doi "https://doi.org/10.1016/j.steroids.2012.02.016" @default.
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