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- W2094675273 abstract "Abstract The barrier to rotation about the phosphorus-nitrogen bond in the bis(dimethylamido) phosphenium cation has been determined by 13C and 1H DNMR complete bandshape analysis and spin saturation transfer methodologies. Arrhenius activation energies for this simple two-site exchange process as derived from the three techniques are 11.2, 11.0 and 12.7 kcal mol−1, respectively. Corresponding activation enthalpies are 10.7, 10.5 and 12.2 kcal mol−1. Activation energies and enthalpies derived from these methods are thus in agreement within 1.7 kcal of one another." @default.
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- W2094675273 date "1988-01-01" @default.
- W2094675273 modified "2023-09-27" @default.
- W2094675273 title "Evaluation of the rotational barrier in the bis-(dimethylamido) phosphenium cation by spin saturation transfer and 1H and 13C complete bandshape analysis" @default.
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- W2094675273 doi "https://doi.org/10.1016/s0020-1693(00)86371-9" @default.
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