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- W2094715280 abstract "The temperature dependences of high-pressure Raman spectra are investigated in the mixed-valence (MV) gold complexes Cs 2 Au 2 X 6 ( X = Cl and Br), which show a pressure-induced phase transition from the MV to single-valence (SV) states. In the SV state at lower temperatures, we observe a broad Raman band at ∼400 cm -1 for X = Cl and at ∼320 cm -1 for X = Br. Judging from their frequencies as well as the significant temperature dependence, we interpret the bands in terms of the formation of the local Au- X 2 - -like state." @default.
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- W2094715280 date "1999-10-01" @default.
- W2094715280 modified "2023-10-16" @default.
- W2094715280 title "Broad Raman Band in the Single-Valence State of Cs<sub><b> 2</b></sub>Au<sub><b> 2</b></sub><i><i>X</i><sub><b> 6</b></sub></i> (<i><i>X</i>=<b> <i>C</i><i>l</i></b></i> and Br)" @default.
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- W2094715280 doi "https://doi.org/10.1143/jpsj.68.3134" @default.
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