Matches in SemOpenAlex for { <https://semopenalex.org/work/W2094720439> ?p ?o ?g. }
Showing items 1 to 76 of
76
with 100 items per page.
- W2094720439 endingPage "1030" @default.
- W2094720439 startingPage "1020" @default.
- W2094720439 abstract "The kinetics of the oxidation of mercury(I) by thallium(III) in aqueous perchloric acid solution, i.e. Hg(I) 2 + Tl(III) → 2Hg(II) + Tl(I), have been examined. The rate law was found to be of the form −d[Hg(I) 2 ]/dt = k exp [Hg(I) 2 ][Tl(III)]/[Hg(II)] where k exp is inversely dependent on the concentrations of H + and of ClO 4 − . The rate-determining step of the reaction appears to be a 'two-electron transfer' between a mercury atom, formed by the dismutation of Hg 2 ++ , and a hydrolyzed thallium ion, i.e. Hg + TlOH ++ → Hg ++ + Tl + + OH − . The rate constant, k, of this reaction is given by k = 10 16±2 exp[−14000 ± 3000/RT] liters mole −1 sec. −1 .H + retards the reaction by opposing the hydrolysis of Tl +++ , while the effect of ClO 4 − appears to be due to its complexing with Hg 2 ++ , Cl − and Br − catalyze the reaction probably by complexing with Hg ++ , thus displacing the Hg 2 ++ dismutation equilibrium, [Formula: see text], to the right and increasing the concentration of Hg atoms. The kinetics and mechanism of the Tl(I)–Tl(III) isotopic electron exchange reaction and of other electron transfer processes in solution are considered in the light of these observations." @default.
- W2094720439 created "2016-06-24" @default.
- W2094720439 creator A5006197764 @default.
- W2094720439 creator A5040265668 @default.
- W2094720439 date "1957-09-01" @default.
- W2094720439 modified "2023-10-16" @default.
- W2094720439 title "KINETICS OF THE OXIDATION OF MERCURY(I) BY THALLIUM (III) IN AQUEOUS SOLUTION" @default.
- W2094720439 doi "https://doi.org/10.1139/v57-139" @default.
- W2094720439 hasPublicationYear "1957" @default.
- W2094720439 type Work @default.
- W2094720439 sameAs 2094720439 @default.
- W2094720439 citedByCount "15" @default.
- W2094720439 countsByYear W20947204392013 @default.
- W2094720439 countsByYear W20947204392021 @default.
- W2094720439 crossrefType "journal-article" @default.
- W2094720439 hasAuthorship W2094720439A5006197764 @default.
- W2094720439 hasAuthorship W2094720439A5040265668 @default.
- W2094720439 hasConcept C121332964 @default.
- W2094720439 hasConcept C123669783 @default.
- W2094720439 hasConcept C147789679 @default.
- W2094720439 hasConcept C148898269 @default.
- W2094720439 hasConcept C161790260 @default.
- W2094720439 hasConcept C178790620 @default.
- W2094720439 hasConcept C179104552 @default.
- W2094720439 hasConcept C184651966 @default.
- W2094720439 hasConcept C185592680 @default.
- W2094720439 hasConcept C199360897 @default.
- W2094720439 hasConcept C2777777548 @default.
- W2094720439 hasConcept C2778161354 @default.
- W2094720439 hasConcept C36663273 @default.
- W2094720439 hasConcept C41008148 @default.
- W2094720439 hasConcept C55904794 @default.
- W2094720439 hasConcept C559099789 @default.
- W2094720439 hasConcept C62520636 @default.
- W2094720439 hasConcept C65024703 @default.
- W2094720439 hasConcept C93391505 @default.
- W2094720439 hasConceptScore W2094720439C121332964 @default.
- W2094720439 hasConceptScore W2094720439C123669783 @default.
- W2094720439 hasConceptScore W2094720439C147789679 @default.
- W2094720439 hasConceptScore W2094720439C148898269 @default.
- W2094720439 hasConceptScore W2094720439C161790260 @default.
- W2094720439 hasConceptScore W2094720439C178790620 @default.
- W2094720439 hasConceptScore W2094720439C179104552 @default.
- W2094720439 hasConceptScore W2094720439C184651966 @default.
- W2094720439 hasConceptScore W2094720439C185592680 @default.
- W2094720439 hasConceptScore W2094720439C199360897 @default.
- W2094720439 hasConceptScore W2094720439C2777777548 @default.
- W2094720439 hasConceptScore W2094720439C2778161354 @default.
- W2094720439 hasConceptScore W2094720439C36663273 @default.
- W2094720439 hasConceptScore W2094720439C41008148 @default.
- W2094720439 hasConceptScore W2094720439C55904794 @default.
- W2094720439 hasConceptScore W2094720439C559099789 @default.
- W2094720439 hasConceptScore W2094720439C62520636 @default.
- W2094720439 hasConceptScore W2094720439C65024703 @default.
- W2094720439 hasConceptScore W2094720439C93391505 @default.
- W2094720439 hasIssue "9" @default.
- W2094720439 hasLocation W20947204391 @default.
- W2094720439 hasOpenAccess W2094720439 @default.
- W2094720439 hasPrimaryLocation W20947204391 @default.
- W2094720439 hasRelatedWork W1964687069 @default.
- W2094720439 hasRelatedWork W1967788951 @default.
- W2094720439 hasRelatedWork W1971445229 @default.
- W2094720439 hasRelatedWork W1989280951 @default.
- W2094720439 hasRelatedWork W2011233279 @default.
- W2094720439 hasRelatedWork W2077993484 @default.
- W2094720439 hasRelatedWork W2088396814 @default.
- W2094720439 hasRelatedWork W2388445837 @default.
- W2094720439 hasRelatedWork W2770645986 @default.
- W2094720439 hasRelatedWork W4232459072 @default.
- W2094720439 hasVolume "35" @default.
- W2094720439 isParatext "false" @default.
- W2094720439 isRetracted "false" @default.
- W2094720439 magId "2094720439" @default.
- W2094720439 workType "article" @default.