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• W2094772964 abstract "It has been observed that when an intermetallic compound-H system is in its two-solid-phase coexistence region, the addition or removal of small aliquots of hydrogen (small driving forces) leads to larger and smaller values of μH respectively, than do large aliquots (large driving forces). It is proposed that the origin of this phenomenon is due to the effect of the interface velocity on the metal atom pile-up at the interface between the dilute and hydride phases. Large aliquots of hydrogen lead to rapid initial interface velocities which can result in the destruction of the pile-up (metal atom equilibrium) at the interface. When the driving pressure during the large aliquot falls below the value needed to maintain v ≥ vc, the pile-up builds up again but does not reach the composition characteristic of small aliquots. It is shown that the chemical potential of hydrogen will be lower during hydriding for the large aliquot case than for the small aliquot case because the hydrogen chemical potential is a function of the metal atom composition at the interface." @default.
• W2094772964 created "2016-06-24" @default.
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• W2094772964 date "1985-12-01" @default.
• W2094772964 modified "2023-09-26" @default.
• W2094772964 title "The Effect of the Interface Velocity on the Plateau Pressure of Intermetallic Compound Hydrides. Theoretical Interpretation" @default.
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• W2094772964 doi "https://doi.org/10.1002/bbpc.19850891212" @default.
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