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- W2094814686 abstract "A study of the structure of sodium borosilicate glasses by optical absorption spectra and the ESR of Cu2+ in these glasses are reported. Their compositions can be expressed as 20Na2OXB2O3(80−X)SiO2 in mol%, where X ranges from 10 to 40. Optical spectra are in good accord with the gaussian distribution. The peak energy shifts slightly. The g∥ value changes in a small way, whereas other spin hamiltonian parameters and the covalency of the Cu2+O bonds can be considered as constants. In addition, the densities of the glasses were also measured. A maximum appears at 20–25 mol% B2O3. The results indicate that complicated structural variations may occur. Moreover, the coexistence of several kinds of structural groups is expected. These may lead to a specific change in density and, at the same time, a small variation in optical absorption and ESR parameters throughout the composition region." @default.
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- W2094814686 date "1982-12-01" @default.
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- W2094814686 title "Optical absorption and ESR of Cu2+ in sodium borosilicate glasses" @default.
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- W2094814686 doi "https://doi.org/10.1016/0022-3093(82)90289-7" @default.
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