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- W2094830643 abstract "We present a study of Langmuir isotherms and 2D bulk moduli of binary lipid mixtures, where changes in monolayer collapse pressure (Πc) are followed while varying the relative amounts of the two components. For monolayers containing dipalmitoylphosphocholine (DPPC) with either hexadecanol (HD) or palmitic acid (PA), a distinctly non-monotonic change in Πc is observed with varying composition. At low mole fractions, there is a slight decrease in Πc as films get richer in DPPC, while a sharp increase to pure DPPC-like values is observed when the mole fraction exceeds ∼0.7. The sudden transition in collapse pressure is explained using the principles of rigidity percolation, and important ramifications of this phenomenon for biological surfactant are discussed." @default.
- W2094830643 created "2016-06-24" @default.
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- W2094830643 date "2006-08-11" @default.
- W2094830643 modified "2023-10-17" @default.
- W2094830643 title "Headgroup Percolation and Collapse of Condensed Langmuir Monolayers" @default.
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- W2094830643 doi "https://doi.org/10.1021/jp061562t" @default.
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