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- W2094835863 abstract "Ciprofloxacin Lactate {4-(3-carboxy-1-cyclopropyl-6-fluoro-1,4-dihydro-4-oxo-7-quinolinyl-)-1-piperazinium-lactate–water(1/1/1.5)}(C20H24N3O6F1·5H2O) belonging to the family of fluoroquinolone antibacterial agents with wide spectrum activity has been studied using single crystal X-ray diffraction techniques. The crystal structure has channels running along crystallographic b-axis with π-stacks of Ciprofloxacin moieties linked through water molecules. A ten-membered hydrogen bonded pattern formed by centrosymmetrically related lactate and water molecules fill the center of the channel. The molecular assembly viewed down the b-axis depicts an infinitely extended open framework channels with the major diameter of about 10.60 Å and minor diameter of 4.79 Å. The structure also has a C–H⋯F intramolecular interaction and an intramolecular hydrogen bond. Analysis of the structures containing 7-piperazin-1-oyl-quinolin-4(1H)-one moiety using the Cambridge Structural Database reveals that a majority of the structures show the propensity to form channels via π⋯π interactions. Also, a detailed comparative study with the structure of magnesium sulfate adduct of ciprofloxacin shows that such interactions lead to similar molecular assemblies." @default.
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- W2094835863 date "2001-01-01" @default.
- W2094835863 modified "2023-09-23" @default.
- W2094835863 title "Hydrogen bonded networks in hydrophilic channels: crystal structure of hydrated Ciprofloxacin Lactate and comparison with structurally similar compounds" @default.
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- W2094835863 doi "https://doi.org/10.1016/s0022-2860(00)00701-8" @default.
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