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- W2094839318 abstract "Seven pyrroles, twenty pyrazines and 2-methyl-5-hydroxy-6-propyl-pyridine have been identified in the CH2Cl2 extract of a heated reaction mixture of d(+)-glucose and aminobutyric acid isomer model systems by gas chromatography-mass spectrometry (GC/MS). Pyrazines, as the main constituent of these reactions, are responsible for the odour properties. Based on an electron spin resonance (ESR) study, the shape and g values of the splitting constant of the ESR spectra of aH = 2·81 Gs, and aN = 8·73 Gs for d(+)-glucose and the 2-aminobutyric and 3-aminobutyric acid model systems, respectively, and of aH = 2·81 Gs, aHα = 5·44 Gs and aN = 8·23 Gs for d(+)-glucose and the 4-aminobutyric acid model system, it can be concluded that the 1,4-dialkylpyrazine cation radicals formed are responsible for pyrazine formation in the initial stage of the non-enzymic browning reaction. The mechanisms of formation of pyrroles, pyrazines and pyridine derivatives are proposed." @default.
- W2094839318 created "2016-06-24" @default.
- W2094839318 creator A5079174056 @default.
- W2094839318 creator A5090093886 @default.
- W2094839318 date "1984-01-01" @default.
- W2094839318 modified "2023-10-18" @default.
- W2094839318 title "The mechanism of pyrrole, pyrazine and pyridine formation in non-enzymic browning reaction" @default.
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- W2094839318 doi "https://doi.org/10.1016/0308-8146(84)90071-2" @default.
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