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- W2094848141 abstract "Abstract The deuterium flow q perm (HD) through a 0.15 mm thick stainless steel membrane at 200°C into vacuum was measured. Deuterium entered the membrane by dissociative adsorption of heavy water (D 2 O) vapour. The q perm (HD) at 200°C caused by this reaction was measured for two equal membranes; for the first a q perm (HD) (200°C) ⩽1.3×10 6 molecules s −1 cm −2 at the partial pressure p (D 2 O)=134 mbar was found while a q perm (HD) (200°C) ⩽3.2×10 6 molecules s −1 cm −2 at p (D 2 O)=168 mbar was found for the second. This flow at 200°C was small compared to the residual hydrogen flow q (H 2 ) from the bulk, ( q perm (HD)/ q (H 2 ) q (H 2 ) and q perm (HD) were thus orders of magnitude lower than the atmospheric hydrogen permeation rate q perm (H 2 ) frequently predicted by existing models, applied to explain the residual q (H 2 ) after particular thermal processing of a ultrahigh vacuum chamber made of austenitic stainless steel. So far, no clear evidence of the relative importance of these two sources has been reported at this temperature. The q perm (D 2 ) was not observed in this experiment." @default.
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- W2094848141 date "2002-10-01" @default.
- W2094848141 modified "2023-09-26" @default.
- W2094848141 title "Deuterium permeation through stainless steel caused by dissociative adsorption of D2O" @default.
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- W2094848141 doi "https://doi.org/10.1016/s0042-207x(02)00386-x" @default.
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