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- W2094848203 abstract "The kinetics of capillary condensation into an initially dry pore is treated as an unsteady diffusion problem with a moving boundary at which the vapor concentration satisfies the Kelvin equation. The (justifiable) approximation that the phenomenon is radial leads to important simplifications. An exact similarity solution is found which is valid for the early stages of the condensation process. An approximate method of analysis is developed, using the class of similarity solutions of the two‐dimensional radial diffusion problem with a constant concentration condition at an appropriately moving boundary. The method has some analogies to the Pohlhausen method in fluid mechanics in that the initial and boundary conditions are satisfied exactly, and the diffusion equation is satisfied in an integral sense. The method depends on numerical methods of integration, but approximate analytical solutions are available when the time is sufficiently large.Numerical solutions are given for the capillary condensation of..." @default.
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- W2094848203 date "1964-08-15" @default.
- W2094848203 modified "2023-10-04" @default.
- W2094848203 title "Kinetics of Capillary Condensation in Wedge‐Shaped Pores" @default.
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- W2094848203 doi "https://doi.org/10.1063/1.1726032" @default.
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