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- W2094848336 abstract "The temperature and pressure dependence of the rate coefficient for H+SO2→OH+SO, which proceeds via the intermediates HSO2 and HOSO, was investigated using a master equation model between 300 and 2000 K and 10−3 and 106 atm. The model provides a simulation of the time dependence of the concentrations of reactants intermediates, and products and allowed the effects caused by the varying temperature, pressure, and the use of different potential energy surfaces to be investigated. The time-dependent species profiles were analyzed with analytical solutions appropriate to high or low temperatures. Limiting rate coefficient expressions obtained are H+SO2→HSO2 k0/cm6 molecule−2 s−1=3.45×10−17(T−5.17)exp(−1563/T) k∞/cm3 molecule−1 s−1=1.76×10−15(T1.48)exp(−594.6/T) H+SO2→HOSO k6/cm6 molecule−2 s−1=7.34×10−10(T−6.43)exp(−5577/T) k∞/cm3 molecule−1 s−1=5.18×10−16(T1.61)exp(−3606/T) H+SO2→OH+SO k/cm3 molecule−1 s−1=1.12×10−2(T−2.22)exp(−15,467/T) HOSO→OH+SO k0/cm3 molecule−1 s−1=1.92×1022(T−9.02)exp(−26,647/T) k∞/s−1=9.94×1021(T−2.54)exp(−38,190/T)" @default.
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- W2094848336 date "2002-01-01" @default.
- W2094848336 modified "2023-10-09" @default.
- W2094848336 title "A master equation model for the determination of rate coefficients in the H+SO2 system" @default.
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- W2094848336 doi "https://doi.org/10.1016/s1540-7489(02)80296-6" @default.
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