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- W2094879595 abstract "One of the requirements for the performance of waste packages prescribed in 10CFR 60.113 is that the high level waste must be {open_quotes}substantially completely{close_quotes} contained for a minimum period of 300 to 1000 years. During this period, the radiation and thermal conditions in the engineered barrier system and the near-field environment are dominated by fission product decay. In the present U.S design of the engineered barrier system, the outer container plays a dominant role in maintaining radionuclide containment. A quantitative methodology for analyzing the performance of the container is described in this paper. This methodology enables prediction of the evolution of the waste package environment in terms of temperature fields, stability of liquid water on the container surface, and concentration of aggressive ions such as chloride. The initiation and propagation of localized corrosion is determined by the corrosion potential of the container material and critical potentials for localized corrosion. The corrosion potential is estimated from the kinetics of the anodic and cathodic reactions including oxygen diffusion through scale layers formed on the container surface. The methodology described is applicable to a wide range of metals, alloys and environmental conditions." @default.
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- W2094879595 date "1994-12-31" @default.
- W2094879595 modified "2023-09-26" @default.
- W2094879595 title "An approach to analysis of high level waste container performance in an unsaturated repository environment" @default.
- W2094879595 hasPublicationYear "1994" @default.
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