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• W2094888265 abstract "Abstract A new complex of formula [Cu(dach) 2 (CCl 3 CO 2 )]CCl 3 CO 2 (dach=1,4-diazacycloheptane) has been synthesised and its crystal structure determined by single-crystal X-ray diffraction. The crystal structure contains two independent copper(II)-centred cations (one disordered) and two trichloroacetate ions. Both copper(II) atoms are pentacoordinate. The chelated 1,4-diazacycloheptane moieties are in a double boat conformation and represent the first structurally characterised example of a trans configuration for two such ligands at a metal centre. The compound was also characterised by IR, electronic and EPR spectra, cyclic voltammetry, and magnetic susceptibility studies." @default.
• W2094888265 created "2016-06-24" @default.
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• W2094888265 date "2000-07-01" @default.
• W2094888265 modified "2023-09-27" @default.
• W2094888265 title "Synthesis, characterisation and crystal structure of a 1,4-diazacycloheptane complex of copper(II)" @default.
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• W2094888265 doi "https://doi.org/10.1016/s0277-5387(00)00480-0" @default.
• W2094888265 hasPublicationYear "2000" @default.
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