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- W2094907411 abstract "Various aromatic nitriles were used for the preparation of the nitrile-capped clusters Fe3(CO)9(μ3-η2-RCN) (2) by reaction with Fe3(CO)12 under hydrogen. Electron-rich nitriles decrease, electron-poor nitriles increase the thermal stability of clusters 2. With CN-substituted pyridines only traces of clusters 2 could be obtained. CO replacement in Fe3(CO)9(PhCN) (2a) by isonitriles also causes a lowering of the stability. Conversely, more stable products were obtained by substitution reaction with trimethyl phosphite. One PPh3 and two dppm derivatives were also obtained. The structure of Fe3(CO)8-P(OMe)3(μ3-η2-PhCN) (5a) was determined." @default.
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- W2094907411 date "1995-08-01" @default.
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- W2094907411 title "Substituted Variants of the Cluster Type Fe <sub>3</sub> (CO) <sub>9</sub> (μ <sub>3</sub> ‐η <sup>2</sup> ‐RCN)" @default.
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- W2094907411 doi "https://doi.org/10.1002/cber.19951280809" @default.
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