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- W2094921272 abstract "The unimolecularity of the thermal dehydrogenation of cyclopentene has been confirmed using the technique of very low-pressure pyrolysis (VLPP). Application of RRKM theory shows that the experimental unimolecular rate constants obtained over the temperature range of 942°–1152°K are consistent with the high-pressure Arrhenius parameters given by where θ = 2.303 RT kcal/mol. These parameters are in good agreement with static and shock tube studies. No firm evidence could be found for any side reactions or reversibility under the experimental conditions used." @default.
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- W2094921272 date "1978-01-01" @default.
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- W2094921272 title "Very low-pressure pyrolysis (VLPP) of cyclopentene" @default.
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- W2094921272 doi "https://doi.org/10.1002/kin.550100110" @default.
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