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- W2094945441 abstract "We report the findings of a supersonic beam investigation of the 1:1 gas phase complexes of indole with various halomethanes. The unique environment of the supersonic jet provides a method by which the pairwise intermolecular interactions of these complexes can be studied without the complications of condensed media effects. The behavior of argon and methane van der Waals molecules is described first in order to provide examples of simple dispersive interactions. These are then contrasted with complexing species such as CF 4 and CCl 4 where repulsive interactions offset the stabilization due to dispersive and dipole – induced dipole forces. Finally, we show that the interaction between the probe molecule and CHCl 3 and CH 2 Cl 2 is apparently hydrogen bonding with the indole π electronic system. The implications of these intermolecular interactions on the area of general anesthesia are discussed in terms of a picture in which both the hydrophobic and polar portions of cell membrane may be reversibly affected." @default.
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- W2094945441 date "1985-07-01" @default.
- W2094945441 modified "2023-10-16" @default.
- W2094945441 title "Supersonic beam investigations of indole and indole–halomethane complexes: intermolecular interactions" @default.
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- W2094945441 doi "https://doi.org/10.1139/v85-257" @default.
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