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- W2094962131 abstract "The oxygen content in Bi2Sr2Ca1Cu2O8+δ and Bi2Sr2Cu3O10+δ superconductor samples is determined using a iodometric titration technique and using a thermogravimetric reduction technique. The reliability of the iodometric oxygen determination was exemplified by the reproducibility of at least 0.01 in δ and the excellent agreement between results obtained separately from iodometry and thermal analysis on a series of samples. Compared to similar determinations in YBa2Cu3O7-δ superconductors, the determination of the metal content is an extra analytical requirement in the case of Bi and Pb containing ceramic materials. For the determination of the metal content, a reproducible and rapid method, based on differential pulse polarography, was optimized. Using EDTA-HCl as supporting electrolyte, we were able to determine the Pb, Bi and Cu content in a single experiment with a relative standard deviation (RSD) < 1 %. Using the techniques mentioned above, we were able to investigate the relationship between Tc and δ in a series of Bi-2212 and Bi-2223 HTSC's. There appears to be a maximum in the Tcvs δ curves for both phases." @default.
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- W2094962131 date "1994-02-01" @default.
- W2094962131 modified "2023-10-16" @default.
- W2094962131 title "On the metal and oxygen content determination in Bi-2212 and Bi-2223 HTSCs" @default.
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- W2094962131 doi "https://doi.org/10.1016/0964-1807(94)90026-4" @default.
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