Matches in SemOpenAlex for { <https://semopenalex.org/work/W2095004662> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W2095004662 endingPage "781" @default.
- W2095004662 startingPage "777" @default.
- W2095004662 abstract "The 1 H nmr spectral parameters for 2-alkylthio derivatives benzaldehyde (alkyl = CH 3 , CH 2 CH 3 , CH(CH 3 ) 2 , C(CH 3 ) 3 ) are used to show that the O-syn conformation of the aldehyde group decreases from 40% for the methyl to zero for the tert-butyl compound in CC1 4 solution at about 300 K. It appears that the alkylthio groups twist out of the benzene plane to the same extent as in the alkyl phenyl sulfides and that it is the concomitant approaches of the 3p lone-pairs on sulfur into the ring plane which, by repulsive interactions with the C=O bond, determine the conformations of the aldehyde group. The spectral parameters display interesting changes as the size of the alkyl group increases. For example, the chemical shift of the aldehydic proton is larger than that reported for any other benzaldehyde derivative in CCl 4 solution." @default.
- W2095004662 created "2016-06-24" @default.
- W2095004662 creator A5011414046 @default.
- W2095004662 creator A5016078655 @default.
- W2095004662 creator A5029767783 @default.
- W2095004662 creator A5069576292 @default.
- W2095004662 date "1985-03-01" @default.
- W2095004662 modified "2023-10-09" @default.
- W2095004662 title "Control of the orientation of the aldehyde group in 2-(alkylthio)benzaldehydes by the directional lone-pair on sulfur" @default.
- W2095004662 doi "https://doi.org/10.1139/v85-128" @default.
- W2095004662 hasPublicationYear "1985" @default.
- W2095004662 type Work @default.
- W2095004662 sameAs 2095004662 @default.
- W2095004662 citedByCount "10" @default.
- W2095004662 crossrefType "journal-article" @default.
- W2095004662 hasAuthorship W2095004662A5011414046 @default.
- W2095004662 hasAuthorship W2095004662A5016078655 @default.
- W2095004662 hasAuthorship W2095004662A5029767783 @default.
- W2095004662 hasAuthorship W2095004662A5069576292 @default.
- W2095004662 hasBestOaLocation W20950046621 @default.
- W2095004662 hasConcept C155647269 @default.
- W2095004662 hasConcept C161790260 @default.
- W2095004662 hasConcept C178790620 @default.
- W2095004662 hasConcept C185592680 @default.
- W2095004662 hasConcept C2777691172 @default.
- W2095004662 hasConcept C2778565081 @default.
- W2095004662 hasConcept C2779692420 @default.
- W2095004662 hasConcept C2779825165 @default.
- W2095004662 hasConcept C2780263894 @default.
- W2095004662 hasConcept C2780378348 @default.
- W2095004662 hasConcept C2781311116 @default.
- W2095004662 hasConcept C32909587 @default.
- W2095004662 hasConcept C46000676 @default.
- W2095004662 hasConcept C518881349 @default.
- W2095004662 hasConcept C71240020 @default.
- W2095004662 hasConceptScore W2095004662C155647269 @default.
- W2095004662 hasConceptScore W2095004662C161790260 @default.
- W2095004662 hasConceptScore W2095004662C178790620 @default.
- W2095004662 hasConceptScore W2095004662C185592680 @default.
- W2095004662 hasConceptScore W2095004662C2777691172 @default.
- W2095004662 hasConceptScore W2095004662C2778565081 @default.
- W2095004662 hasConceptScore W2095004662C2779692420 @default.
- W2095004662 hasConceptScore W2095004662C2779825165 @default.
- W2095004662 hasConceptScore W2095004662C2780263894 @default.
- W2095004662 hasConceptScore W2095004662C2780378348 @default.
- W2095004662 hasConceptScore W2095004662C2781311116 @default.
- W2095004662 hasConceptScore W2095004662C32909587 @default.
- W2095004662 hasConceptScore W2095004662C46000676 @default.
- W2095004662 hasConceptScore W2095004662C518881349 @default.
- W2095004662 hasConceptScore W2095004662C71240020 @default.
- W2095004662 hasIssue "3" @default.
- W2095004662 hasLocation W20950046621 @default.
- W2095004662 hasOpenAccess W2095004662 @default.
- W2095004662 hasPrimaryLocation W20950046621 @default.
- W2095004662 hasRelatedWork W1533372989 @default.
- W2095004662 hasRelatedWork W1969295444 @default.
- W2095004662 hasRelatedWork W2047324127 @default.
- W2095004662 hasRelatedWork W2085733584 @default.
- W2095004662 hasRelatedWork W2362801003 @default.
- W2095004662 hasRelatedWork W2366650074 @default.
- W2095004662 hasRelatedWork W2370437360 @default.
- W2095004662 hasRelatedWork W2413936414 @default.
- W2095004662 hasRelatedWork W2581564447 @default.
- W2095004662 hasRelatedWork W4319263624 @default.
- W2095004662 hasVolume "63" @default.
- W2095004662 isParatext "false" @default.
- W2095004662 isRetracted "false" @default.
- W2095004662 magId "2095004662" @default.
- W2095004662 workType "article" @default.