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- W2095027669 abstract "Abstract The kinetics and mechanism of reactions of (2,2′-dipyridyl)W(CO)4 with SnCl4, (C6H5)SnCl3, (n-C4H9)SnCl3 and (C6H5)2SnCl2, and of (o-phenanthroline)Mo(CO)4 with GeI4 have been investigated employing stopped flow and conventional kinetic techniques. The oxidizing agent-dependent rate laws are encompassed in a mechanism which involves reversible addition of two successive molecules of the oxidant to the substrate, followed by other, rapid, steps. For the reaction of (C6H5SnCl2 with (dipy)W(CO)4 at 95–115°, a parallel reaction path probably involving rate-determining dissociation of CO was also observed. Rates were found to be very sensitive to the nature of the substituents bonded to the Group IV-A metal, being greatest for electron-withdrawing substituents. Different rate laws were observed for reactions which yielded products of different stereochemistries." @default.
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- W2095027669 date "1973-03-01" @default.
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- W2095027669 title "OCTAHEDRAL METAL CARBONYLS. XXVIII.<sup>1</sup> KINETICS AND MECHANISM OF OXIDATIVE ELIMINATION REACTIONS OF SUBSTITUTED GROUP VI-B METAL CARBONYLS WITH TIN- AND GERMANIUM-CONTAINING OXIDIZING AGENTS" @default.
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- W2095027669 doi "https://doi.org/10.1080/00958977308072987" @default.
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