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- W2095038632 abstract "Cocondensation of chromium atoms with phenanthrene vapor affords bisη 1,2,3,4,10a,4a - phenanthrene)chromium (4). 1 NMR spectroscopy reveals, that the diastereomers 4 (rac) and 4' (meso) are formed in a 2:1 ratio. Cyclic voltammetric studies on 4 show, that four oxidation states are accessible: [E° ═ -2.235 (rev.), -0.651 (rev.), + 0.82 (irrev.) V vs. SCE]. The radical ions are characterized by ESR spectroscopy in fluid and rigid solutions. Prominent feature of these species is the inverse relative magnitude of the g-tensor components: ." @default.
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- W2095038632 date "1983-11-01" @default.
- W2095038632 modified "2023-09-26" @default.
- W2095038632 title "Metall-π-Komplexe von Benzolderivaten, XX [1]. Über die Cokondensation des Phenanthrens mit Chromatomen - Reaktivität, Redoxverhalten, ESR-und NMR-spektroskopische Untersuchungen / Metal-π-Complexes of Benzene Derivatives, XX [1]. Cocondensation of Phenanthrene with Chromium Atoms - Reactivity, Redox Behavior, ESR and NMR Spectroscopic Investigation" @default.
- W2095038632 doi "https://doi.org/10.1515/znb-1983-1107" @default.
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