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- W2095073696 abstract "Abstract Electroconductive poly( N ‐butylaniline)–lignosulfonate (PBA–LS) composite nanospheres were prepared in a facile way by in situ, unstirred polymerization of N ‐butylaniline with lignosulfonate (LS) as a dispersant and dopant. The LS content was used to optimize the size, structure, electroconductivity, solubility, and silver ion adsorptive capacity of the PBA–LS nanospheres. Uniform PBA–LS10 nanospheres with a minimal mean diameter of 375 nm and high stability were obtained when the LS content was 10 wt %. The PBA–LS10 nanospheres possess an increased electroconductivity of 0.109 S cm −1 compared with that of poly( N ‐butylaniline) (0.0751 S cm −1 ). Furthermore, the PBA–LS10 nanospheres have a maximal silver‐ion sorption capacity of 815.0 mg g −1 at an initial silver ion concentration of 50 mmol L −1 (25 °C for 48 h), an enhancement of 70.4 % compared with PBA. Moreover, a sorption mechanism of silver ions on the PBA–LS10 nanospheres is proposed. TEM and wide‐angle X‐ray diffraction results showed that silver nanoparticles with a diameter size range of 6.8–55 nm was achieved after sorption, indicating that the PBA–LS10 nanospheres had high reductibility for silver ions." @default.
- W2095073696 created "2016-06-24" @default.
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- W2095073696 date "2012-10-25" @default.
- W2095073696 modified "2023-10-18" @default.
- W2095073696 title "Controlled Preparation and Reactive Silver-Ion Sorption of Electrically Conductive Poly(<i>N</i>-butylaniline)-Lignosulfonate Composite Nanospheres" @default.
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- W2095073696 doi "https://doi.org/10.1002/chem.201202203" @default.
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