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- W2095087408 abstract "A series of bimetallic complexes of general formula [(phen)Re(CO)(3)LOs(trpy)(bpy)](3+) (bpy = 2,2'-bipyridine, phen = 1,10-phenanthroline, trpy = 2,2':6',2' '-terpyridine, and L = 4,4'-bipyridine (4,4'-bpy), trans-1,2-bis(4-pyridyl)ethylene (t-bpe), or 1,2-bis(4-pyridyl)ethane (bpa)) and the model mononuclear species [(phen)Re(CO)(3)L](+) and [Os(trpy)(bpy)L](2+) have been synthesized and their photophysical and photochemical properties studied. In the binuclear species an efficient Re(I)-Os(II) energy transfer is observed, which is analyzed in terms of Förster theory. In the binuclear [(phen)Re(CO)(3)(t-bpe)Os(trpy)(bpy)](3+) complex, the trans to cis isomerization of the coordinated t-bpe ligand, characteristic of the [(phen)Re(CO)(3)(t-bpe)](+) subunit, is inhibited by competitive intramolecular energy transfer." @default.
- W2095087408 created "2016-06-24" @default.
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- W2095087408 date "2001-12-01" @default.
- W2095087408 modified "2023-10-14" @default.
- W2095087408 title "Intramolecular Energy Transfer Processes in Binuclear Re−Os Complexes" @default.
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- W2095087408 doi "https://doi.org/10.1021/ic010224y" @default.
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