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- W2095087883 abstract "In (8-dimethylamino-naphth-1-yl) (‘DAN’) carbinols DAN–C(OH)R1R2, the N atom can approach the HO group unto N⋯H-O hydrogen bond distance only when the steric conditions are favourable. The energy gain of such N⋯H–O interactions is insufficient to force R1 and R2 into otherwise unfavourable conformations. The geometry of the naphthalene may cause N, O and C atoms to reside in positions similar to those typical for hydrogen bonds though no N⋯H–O and N⋯H–C hydrogen bonds may actually be involved. By analogy, it seems unlikely that in peri-donor/acceptor substituted naphthalenes D–C10H6–A dative interactions (D→A) of similar or less energy as such N⋯H-O interactions can interfere with the geometry conserving forces of naphthalene and the steric effects of the peri substituents." @default.
- W2095087883 created "2016-06-24" @default.
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- W2095087883 date "2005-09-01" @default.
- W2095087883 modified "2023-10-17" @default.
- W2095087883 title "peri-Interactions in naphthalenes, 13 8-Dimethylamino-naphth-1-yl carbinols as model systems for potential N→Si/P interactions" @default.
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- W2095087883 doi "https://doi.org/10.1016/j.molstruc.2005.04.042" @default.
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