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- W2095092014 abstract "Abstract The tri-n-butylstannyl alkoxides (TBSA) of benzhydrols were prepared by treating the alcohols with tri-n-butyltin oxide (TBTO) and azeotropically removing the water. They were oxidised by bromine in carbon tetrachloride to the corresponding ketones. The oxidation was found to be a second order process. The effect of substituents on the rate was studied and the Hammett ϱ was found to be − 2.55 at 308 K. A mechanism is proposed." @default.
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- W2095092014 date "1988-04-01" @default.
- W2095092014 modified "2023-10-05" @default.
- W2095092014 title "Kinetics and mechanism of oxidation of tri-n-butylstannyl alkoxides of benzhydrol and substituted benzhydrols by bromine in carbon tetrachloride" @default.
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- W2095092014 doi "https://doi.org/10.1016/0022-328x(88)80182-7" @default.
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