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• W2095120070 abstract "A transition-metal-free radical phosphonation using Me3SnPPh2 and the less toxic Me3SiPPh2 is reported. These readily available reagents react highly efficiently with primary and secondary alkyl radicals. Moreover, aryl radicals and tertiary alkyl radicals are phosphonated with Me3SnPPh2 (see scheme; R=aryl, alkyl, vinyl; X=I, Br, OC(S)imidazolyl). DFT calculations provide insights into the mechanism of the reaction. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z701650_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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• W2095120070 date "2007-08-20" @default.
• W2095120070 modified "2023-10-18" @default.
• W2095120070 title "Homolytic Substitution at Phosphorus for the Synthesis of Alkyl and Aryl Phosphanes" @default.
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• W2095120070 doi "https://doi.org/10.1002/anie.200701650" @default.
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