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- W2095124857 abstract "By measuring the isotope shifts of the rotational gR-factors of different isotopic species the electric dipole moment of the molecular ion KrH+ was determined. For that purpose we studied the Zeeman effect of the J = 1 ← 0 transition of KrH+ at 494.5 GHz and the J = 2 ← 1 transition of KrD+ at 503 GHz. In a magnetic field of 4.950 T the rotational transition splits into two ΔM = ±1 components, resulting in splittings of approximately 41.8 MHz (KrH+) and 21.1 MHz (KrD+). It turned out that there is a major influence of the zero-point vibrations on the experimentally determined electric dipole moment, which results in an uncertainty of the interpretation of the experimental data. The ions were generated in a modified anomalous discharge placed in a superconducting magnet. The transitions were observed by direct absorption of the harmonics of a 70-GHz klystron, using the tunable FIR sideband spectrometer at Nijmegen university." @default.
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- W2095124857 date "1992-05-01" @default.
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- W2095124857 title "Determination of the electric dipole moment of KrH+" @default.
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- W2095124857 doi "https://doi.org/10.1016/0022-2852(92)90505-i" @default.
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