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- W2095127110 abstract "The preparation and structural characterization of an elusive geometrical isomer of dirhodium(II) tetrakis[methyl 1-acetyl-2-oxoimidazolidine-4(S)-carboxylate], Rh2(4S-MACIM)4, has been achieved. The imidazolidinone ligands are arrayed around the dirhodium(II) core with four nitrogen donor atoms bound to one rhodium and four oxygens bound to the other (4,0). The crystal structure of this compound has been determined to be that of (4,0)-Rh2(4S-MACIM)4(CH3CN)2d(CH3CN): space group P2(in1) with cell constants a = 11.518(4), b = 16.851(2), c = 11.573(3) Å, V = 2155.4(6) Å3, Z = 2,R = 0.0295, RhRh distance = 2.4547(6) Å. Prepared by ligand substitution on Rh2(OAc)4, (4,0)-Rh2(4s-MACIM)4 was isolated in 25% yield, but this compound isomerizes to its (2,2-cis)- and (3,1)-isomers under the reaction conditions. Racemic products were obtained from catalytic uses of (4,0)-Rh2(4S-MACIM)4 in diazo decomposition reactions." @default.
- W2095127110 created "2016-06-24" @default.
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- W2095127110 date "1997-12-01" @default.
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- W2095127110 title "(4,0)-Dirhodium(II) tetrakis[methyl 1-acetyl-2-oxoimidazolidine-4(S)-carboxylate]. Implications for the mechanism of ligand exchange reactions" @default.
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- W2095127110 doi "https://doi.org/10.1016/s0020-1693(97)05525-4" @default.
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