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• W2095150584 startingPage "971" @default.
• W2095150584 abstract "We performed partial oxidation, steam reforming, and CO2 reforming of CH4 to synthesis gas, using oxidized-diamond-supported group VIII metal catalysts, to investigate the properties of oxidized diamond as a support material and to avoid carbon deposition on a metal-loaded catalyst. Nickel (5 wt %)/oxidized diamond afforded the highest CH4 conversion of 24% (CH4/O2 = 5), giving CO and H2 at 873 K for the partial oxidation of CH4. No carbon deposition was observed with a supported oxidized-diamond catalyst (5 wt % nickel loading level) in the partial oxidation of CH4 at >923 K. In the steam reforming of CH4, ruthenium (5 wt %)/oxidized diamond afforded a CH4 conversion of 63% (CH4/H2O = 0.33), giving CO and H2 at 873 K. Nickel, palladium, ruthenium, and rhodium (5 wt %)/oxidized diamond showed high catalytic activities for CO2 reforming of CH4 (CH4/CO2 = 1) at 873 K." @default.
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• W2095150584 date "2003-06-20" @default.
• W2095150584 modified "2023-10-16" @default.
• W2095150584 title "Synthesis Gas Production from Methane Using Oxidized-Diamond-Supported Group VIII Metal Catalysts" @default.
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• W2095150584 doi "https://doi.org/10.1021/ef0300040" @default.
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