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- W2095155809 abstract "The infrared spectra from 4000 to 50cm−1 of copper(II)-cobalt(II) hydroxide nitrate mixed crystals, CuxCo2 − x(OH)3NO3 (0.0 < x < 2.0) were obtained. The spectra are generally complex due to the formation of disordered solid solutions and the distorted octahedral coordination of copper(II). The experimentally observed frequencies were interpreted in terms of increasing NO3 polarization, decreasing metal-oxygen force constants and weakening of the hydrogen bonds upon substitution of cobalt for copper. The spectroscopic data are in good agreement with the recently reported structural disorder in these phases." @default.
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- W2095155809 date "1990-01-01" @default.
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- W2095155809 title "Infrared spectra of Cu(II)-Co(II) mixed hydroxide nitrates" @default.
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- W2095155809 doi "https://doi.org/10.1016/0022-3697(90)90102-l" @default.
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