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- W2095158370 abstract "A series of five complexes of tin(IV) with 5,10,15,20-tetraphenylporphyrin (H2tpp) of the type [SnX2(tpp)] has been prepared and characterized using NMR and single crystal X-ray diffraction techniques. The complexes are [Sn(OH)2(tpp)] (1), [Sn(OH2)2(tpp)] (CF3SO3)2 (2), [Sn(C6H5CO2)2(tpp)] (3), [Sn(2-OH-C6H4CO2)2(tpp)] (4) and [Sn(2-OCOCH3-C6H4CO2)2(tpp)] (5). All complexes are monomeric with little structural variation within the Sn(tpp) framework. All axial substituents act as unidentate ligands with the SnO bond lengths varying from 2.017(4) Å (X = OH) (1) through 2.055(5) Å (3), 2.06(3) Å (mean) (5), 2.09(1) Å (4) (the substituted benzoates) to 2.16(1) Å (mean) (X = OH2) (2)." @default.
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- W2095158370 date "1991-01-01" @default.
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- W2095158370 title "Tin(IV) porphyrin complexes—IV. Crystal structures of meso-tetraphenylporphyrinatotin(IV) complexes with hydroxide, water, benzoate, salicylate and acetylsalicylate as axial ligands" @default.
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- W2095158370 doi "https://doi.org/10.1016/s0277-5387(00)80221-1" @default.
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