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- W2095181503 abstract "An ESR spectrum of inactive catechol 1,2-oxygenase (catechol: O2 1,2-oxidoreductase, EC 1.13.1.1, formerly known as pyrocatechase) was measured and found to be an anisotropic one. These g-values were estimated to be gx = 3.87, gy = 4.41 and gz = 4.07, whereas that of active catechol 1,2-oxygenase is g = 4.28, which was degenerated. Comparing the theoretical g-values, which were calculated by Aasaet al., with the experimental ones, the E- and D-terms in spin-Hamiltonian were estimated to be 0.19 cm−1 and 0.021 cm−1, respectively. From theoretical considerations, the inactivation mechanisms seems to be the displacement of one of ligands on iron." @default.
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- W2095181503 date "1967-11-01" @default.
- W2095181503 modified "2023-10-17" @default.
- W2095181503 title "Studies on mechanism of inactivation of catechol 1,2-oxygenase by electron spin resonance" @default.
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- W2095181503 doi "https://doi.org/10.1016/0005-2744(67)90225-2" @default.
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