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- W2095190615 abstract "Abstract A new supramolecular self‐assembly approach to construct micelles and reverse micelles was reported. Double‐hydrophilic block copolymers poly(ethylene oxide)‐ b ‐poly( N ‐isopropylacrylamide) (PEO‐ b ‐PNIPAAm) was synthesized via atom transfer radical polymerization (ATRP) using PEO macroinitiator. Because of the lower critical solution temperature (LCST) phase behavior of PNIPAAm, PEO‐ b ‐PNIPAAm block copolymers self‐assembled to form PNIPAAm‐core micelles at 40°C. The PNIPAAm‐core micelles were disassembled to unimers when the temperature was decreased to 25°C. But the addition of α ‐cyclodextrins ( α ‐CDs) could induce the formation of PNIPAAm‐shell micelles because of the channel‐type crystallities induced by PEO/ α ‐CDs polyrotaxanes. The assembly and disassembly procedure of micelles and reverse micelles were investigated by dynamic light scattering (DLS), X‐ray diffraction (XRD), 1 H NMR and transmission electron microscopy (TEM)." @default.
- W2095190615 created "2016-06-24" @default.
- W2095190615 creator A5007028732 @default.
- W2095190615 creator A5024704265 @default.
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- W2095190615 date "2013-11-28" @default.
- W2095190615 modified "2023-09-25" @default.
- W2095190615 title "Supramolecular Micelles and Reverse Micelles Based on Cyclodextrin Polyrotaxanes" @default.
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- W2095190615 doi "https://doi.org/10.1002/cjoc.201300742" @default.
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