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• W2095209892 abstract "Complexes with Sterically Demanding Ligands, V. – Synthesis of 4-tert-Butyl-1,2-bis(trimethylsilyl) cyclopentadienyl Complexes of Iron and Cobalt 2-tert-Butyl-5,5-bis(trimethylsilyl)-2,4-cyclopentadiene (1) is prepared in a one-pot synthesis starting from 1,1-dimethylfulvene. Deprotonation of 1 with n-butyllithium yields the lithium derivative Li[C5H2(CMe3)(SiMe3)2] (2) which is treated with FeBr2· DME and CO to cleanly give [C5H2(CMe3)(SiMe3)2]Fe(CO)2Br (3). Ferrocene and cobaltocenium cation derivatives [C5H2-(CMe3)(SiMe3)2]2M (M = Fe: 4; M = Co⊕ PF6⊖: 5) have also been synthesized using 2. Variable-temperature 1H-NMR spectroscopy shows that rotation of the five-membered ring about the metal-ring axis is hindered in these metallocenes." @default.
• W2095209892 created "2016-06-24" @default.
• W2095209892 creator A5002636361 @default.
• W2095209892 date "1989-06-01" @default.
• W2095209892 modified "2023-10-16" @default.
• W2095209892 title "Komplexe mit sterisch anspruchsvollen Liganden, V. Synthese von 4‐ <i>tert</i> ‐Butyl‐1,2‐bis(trimethylsilyl)cyclopentadienyl‐Komplexen des Eisens und Cobalts" @default.
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• W2095209892 doi "https://doi.org/10.1002/cber.19891220612" @default.
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