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• W2095211312 abstract "Au(III) and Pd(II) chloride complexes with N(1),O-chelating 2-acetylpyridine (2apy) and N(1)- monodentately binding 2-benzoylpyridine (2bz′py)-[Pd(2apy)Cl 2 ], [Au(2bz′py)Cl 3 ], trans -[Pd(2bz′py) 2 Cl 2 ], as well as Au(III) chloride organometallics with monoanionic forms of 2apy or 2bz′py, deprotonated at the acetyl or benzyl side groups (2apy*, 2bz′py*)-[Au(2apy*)Cl 2 ], [Au(2bz′py*)Cl 2 ], were studied by 1 H, 13 C, and 15 N NMR. 1 H, 13 C, and 15 N coordination shifts (i.e., differences between the respective , , and chemical shifts of the same atom in the complex and ligand molecules: , , ) were discussed in relation to the molecular structures and coordination modes, as well as to the factors potentially influencing nuclear shielding. Analogous NMR measurements were performed for the new (2bz′pyH)[AuCl 4 ] salt." @default.
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• W2095211312 date "2013-01-01" @default.
• W2095211312 modified "2023-10-17" @default.
• W2095211312 title "¹H,¹³C, and¹⁵N NMR Studies of Au(III) and Pd(II) Chloride Complexes and Organometallics with 2-Acetylpyridine and 2-Benzoylpyridine" @default.
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• W2095211312 doi "https://doi.org/10.1155/2013/982832" @default.
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