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- W2095243721 abstract "An actinometer system was developed in which a solute (azoxybenzene) was photolysed in a relatively massive block of poly(methyl methacrylate) (PMMA). Pieces which fitted directly into the cuvette holder of a spectrophotometer were cut from sheets of this material. The initially colourless pieces of polymer were photolysed, and the product (o-hydroxyazobenzene) was monitored by measuring its absorbance at 420 nm (ϵ = 4500 dm3 mol−1 cm−1). The quantum yield of this photorearrangement had a value of 4.2 × 10−3, and an empirical relationship allowed the total photon dose incident on any sample to be estimated using a single absorbance measurement. Investigations of other potential solutes revealed that this technique of using PMMA blocks which contain residual monomer is applicable only to photoreactions that do not proceed through free-radical intermediates." @default.
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- W2095243721 date "1983-01-01" @default.
- W2095243721 modified "2023-10-18" @default.
- W2095243721 title "A solid state actinometer based on the photorearrangement of azoxybenzene in poly(methyl methacrylate)" @default.
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- W2095243721 doi "https://doi.org/10.1016/0047-2670(83)80062-8" @default.
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