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• W2095278317 endingPage "084304" @default.
• W2095278317 startingPage "084304" @default.
• W2095278317 abstract "The dissociative electron attachment to the gas phase nucleobase adenine is studied using two different experiments. A double focusing sector field mass spectrometer is utilized for measurements requiring high mass resolution, high sensitivity, and relative ion yields for all the fragment anions and a hemispherical electron monochromator instrument for high electron energy resolution. The negative ion mass spectra are discussed at two different electron energies of 2 and 6eV. In contrast to previous gas phase studies a number of new negative ions are discovered in the mass spectra. The ion efficiency curves for the negative ions of adenine are measured for the electron energy range from about 0to15eV with an electron energy resolution of about 100meV. The total anion yield derived via the summation of all measured fragment anions is compared with the total cross section for negative ion formation measured recently without mass spectrometry. For adenine the shape of the two cross section curves agrees well, taking into account the different electron energy resolutions; however, for thymine some peculiar differences are observed." @default.
• W2095278317 created "2016-06-24" @default.
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• W2095278317 date "2006-08-28" @default.
• W2095278317 modified "2023-10-01" @default.
• W2095278317 title "High resolution dissociative electron attachment to gas phase adenine" @default.
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• W2095278317 doi "https://doi.org/10.1063/1.2336775" @default.
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• W2095278317 hasPublicationYear "2006" @default.
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