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- W2095282954 abstract "We successfully synthesized a new homologous compound series, (Fe,Cu)Sr2(Y,Ce)nCu2O4+2n+z (z∼1.0). The crystal structures of the compounds with n=1−3 were refined by the Rietveld analysis of X-ray powder diffraction data and the compounds with n≥4 were analyzed by a high-resolution transmission electron microscope eHRTEM). The compound with n=1, (Fe,Cu)Sr2YCu2O6+z has triple-perovskite (tetragonal YBa2Cu3O6+z-type) structure and those with n≥2 consist o triple-perovskite blocks, (Fe,Cu)Sr2(Y,Ce)Cu2O6+z, and fluorite blocks, [(Y,Ce)O2]n−1. The number, (n−1), corresponds to the thickness of the fluorite block. The compound with n=1 exhibited superconductivity and those with n≥2 were semiconductive. The crystal structures and superconducting properties of these homologous series compounds are discussed from a crystal chemical point of view." @default.
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- W2095282954 date "1992-03-01" @default.
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- W2095282954 title "Homologous compound series containing multiple-MO2-unit fluorite block, (Fe, Cu)Sr2 (Y, Ce)nCu2O4+2n+z(n=1,2,3,·,and z∼1)" @default.
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- W2095282954 doi "https://doi.org/10.1016/0921-4534(92)90759-6" @default.
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