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- W2095286861 abstract "Synthetically straightforward conditions have been developed for the preparation of poly(bis 2,2,2-trifluoroethoxy)phosphazene with low PDI (<1.15) at high conversion (75-99%) and on a multigram scale. A combination of 31P NMR and GPC analyses demonstrate that molecular weight increases linearly as a function of monomer consumption, exhibiting first order kinetics with respect to monomer concentration up to high monomer conversion. Thus, the molecular weight can be controlled by varying the initiator (H2O) to monomer ratio." @default.
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- W2095286861 date "2014-05-29" @default.
- W2095286861 modified "2023-09-27" @default.
- W2095286861 title "Robust and Operationally Simple Synthesis of Poly(bis(2,2,2-trifluoroethoxy) phosphazene) with Controlled Molecular Weight, Low PDI, and High Conversion" @default.
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- W2095286861 doi "https://doi.org/10.1021/mz500199x" @default.
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