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- W2095304326 abstract "Electron-paramagnetic-resonance spectra of ${mathrm{Mn}}^{2+}$ in single crystals of ${mathrm{Cd}}_{2}$Zr ${mathrm{F}}_{8}$ensuremath{cdot}${6mathrm{H}}_{2}$O have been recorded at room temperature. An abundance of $^{19}mathrm{F}$ ligand hyperfine structure has been observed for all the 30 ${mathrm{Mn}}^{2+}$ hyperfine lines at all orientations of the crystals. From the angular-variation study of $^{19}mathrm{F}$ superhyperfine structure it has been concluded that the impurity ion shows a preferential occupation of ${mathrm{ZrF}}_{8}^{4mathrm{ensuremath{-}}}$ site over that of [${mathrm{CdF}}_{4}$(${mathrm{H}}_{2}$O${)}_{3}$${]}^{2mathrm{ensuremath{-}}}$. This is due to the identical ionic radius of ${mathrm{Zr}}^{4+}$ and ${mathrm{Mn}}^{2+}$ (0.80 AA{}) while the ${mathrm{Cd}}^{2+}$ ionic radius is much larger (0.99 AA{}). This is an instance where ${mathrm{Mn}}^{2+}$ has replaced ${mathrm{Zr}}^{4+}$ in a lattice where ${mathrm{Cd}}^{2+}$ was available and an isostructural ${mathrm{Mn}}_{2}$${mathrm{ZrF}}_{8}$ensuremath{cdot}${6mathrm{H}}_{2}$O was known to exist. A qualitative evaluation of the spin-Hamiltonian parameters has been carried out." @default.
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- W2095304326 title "<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mmultiscripts><mml:mrow><mml:mi mathvariant=normal>F</mml:mi></mml:mrow><mml:mprescripts /><mml:mrow /><mml:mrow><mml:mn>19</mml:mn></mml:mrow><mml:mrow /><mml:mrow /></mml:mmultiscripts></mml:mrow></mml:math>ligand hyperfine structure in the room-temperature electron-paramagnetic-resonance spectra of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msup><mml:mrow><…" @default.
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- W2095304326 doi "https://doi.org/10.1103/physrevb.51.1294" @default.
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