FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2095306247> ?p ?o ?g. }

• W2095306247 endingPage "11319" @default.
• W2095306247 startingPage "11318" @default.
• W2095306247 abstract "Mg metal reduction of the divalent precursor PdCl2(CNArDipp2)2 (Dipp = 2,6-diisopropylphenyl) provides the isolable, two-coordinate Pd(0) bis-isocyanide, Pd(CNArDipp2)2, which is the first stable monomeric isocyanide complex of zerovalent palladium. Variable temperature 1H NMR and FTIR studies on Pd(CNArDipp2)2 in the presence of added CNArDipp2 revealed that free and coordinated isocyanide undergo rapid exchange, but the components do not form a stable tris-isocyanide complex. Bis-isocyanide Pd(CNArDipp2)2 is active for oxidative addition reactions and readily reacts with benzyl chloride and mesityl bromide to form Pd(Cl)(Bz)(CNArDipp2)2 and Pd(Br)(Mes)(CNArDipp2)2, respectively. Room-temperature Suzuki−Miyaura cross-coupling reactions are mediated by Pd(CNArDipp2)2. Coordinatively and electronically unsaturated substrates also react with Pd(CNArDipp2)2. Addition of thallium(I) triflate (TlOTf) to Pd(CNArDipp2)2 results in the salt [TlPd(CNArDipp2)2]OTf, while addition of O2 results in the peroxo complex (η2-O)Pd(CNArDipp2)2. Most remarkably, 2 equiv of nitrosobenzene react with Pd(CNArDipp2)2 to form the square planar complex (κ1-N-PhNO)2 Pd(CNArDipp2)2, the geometry of which strongly suggests the formation of a divalent Pd center. With the aid of density functional theory calculations, this valence change is rationalized in terms of a formal reduction of the bond order in each NO unit to 1.5." @default.
• W2095306247 created "2016-06-24" @default.
• W2095306247 creator A5022058969 @default.
• W2095306247 creator A5024980300 @default.
• W2095306247 creator A5057803757 @default.
• W2095306247 creator A5087270254 @default.
• W2095306247 date "2009-07-24" @default.
• W2095306247 modified "2023-10-18" @default.
• W2095306247 title "Bond Activation, Substrate Addition and Catalysis by an Isolable Two-Coordinate Pd(0) Bis-Isocyanide Monomer" @default.
• W2095306247 cites W1967620487 @default.
• W2095306247 cites W1977167776 @default.
• W2095306247 cites W1978890358 @default.
• W2095306247 cites W1979567315 @default.
• W2095306247 cites W1981712030 @default.
• W2095306247 cites W1984443047 @default.
• W2095306247 cites W1995387931 @default.
• W2095306247 cites W1998537076 @default.
• W2095306247 cites W2014795938 @default.
• W2095306247 cites W2019069997 @default.
• W2095306247 cites W2022115412 @default.
• W2095306247 cites W2027329838 @default.
• W2095306247 cites W2047893591 @default.
• W2095306247 cites W2050106385 @default.
• W2095306247 cites W2054550793 @default.
• W2095306247 cites W2056574270 @default.
• W2095306247 cites W2078818614 @default.
• W2095306247 cites W2083236090 @default.
• W2095306247 cites W2089861124 @default.
• W2095306247 cites W2119688276 @default.
• W2095306247 cites W2130308044 @default.
• W2095306247 cites W2165145376 @default.
• W2095306247 cites W2949739759 @default.
• W2095306247 cites W2952393861 @default.
• W2095306247 cites W3005389570 @default.
• W2095306247 cites W4247648342 @default.
• W2095306247 doi "https://doi.org/10.1021/ja905338x" @default.
• W2095306247 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19630396" @default.
• W2095306247 hasPublicationYear "2009" @default.
• W2095306247 type Work @default.
• W2095306247 sameAs 2095306247 @default.
• W2095306247 citedByCount "79" @default.
• W2095306247 countsByYear W20953062472012 @default.
• W2095306247 countsByYear W20953062472013 @default.
• W2095306247 countsByYear W20953062472014 @default.
• W2095306247 countsByYear W20953062472015 @default.
• W2095306247 countsByYear W20953062472016 @default.
• W2095306247 countsByYear W20953062472017 @default.
• W2095306247 countsByYear W20953062472018 @default.
• W2095306247 countsByYear W20953062472019 @default.
• W2095306247 countsByYear W20953062472020 @default.
• W2095306247 countsByYear W20953062472021 @default.
• W2095306247 countsByYear W20953062472022 @default.
• W2095306247 countsByYear W20953062472023 @default.
• W2095306247 crossrefType "journal-article" @default.
• W2095306247 hasAuthorship W2095306247A5022058969 @default.
• W2095306247 hasAuthorship W2095306247A5024980300 @default.
• W2095306247 hasAuthorship W2095306247A5057803757 @default.
• W2095306247 hasAuthorship W2095306247A5087270254 @default.
• W2095306247 hasConcept C155647269 @default.
• W2095306247 hasConcept C161790260 @default.
• W2095306247 hasConcept C178790620 @default.
• W2095306247 hasConcept C185592680 @default.
• W2095306247 hasConcept C21774173 @default.
• W2095306247 hasConcept C2777010268 @default.
• W2095306247 hasConcept C2778478478 @default.
• W2095306247 hasConcept C2778815869 @default.
• W2095306247 hasConcept C502130503 @default.
• W2095306247 hasConcept C71240020 @default.
• W2095306247 hasConcept C75473681 @default.
• W2095306247 hasConcept C94882840 @default.
• W2095306247 hasConceptScore W2095306247C155647269 @default.
• W2095306247 hasConceptScore W2095306247C161790260 @default.
• W2095306247 hasConceptScore W2095306247C178790620 @default.
• W2095306247 hasConceptScore W2095306247C185592680 @default.
• W2095306247 hasConceptScore W2095306247C21774173 @default.
• W2095306247 hasConceptScore W2095306247C2777010268 @default.
• W2095306247 hasConceptScore W2095306247C2778478478 @default.
• W2095306247 hasConceptScore W2095306247C2778815869 @default.
• W2095306247 hasConceptScore W2095306247C502130503 @default.
• W2095306247 hasConceptScore W2095306247C71240020 @default.
• W2095306247 hasConceptScore W2095306247C75473681 @default.
• W2095306247 hasConceptScore W2095306247C94882840 @default.
• W2095306247 hasIssue "32" @default.
• W2095306247 hasLocation W20953062471 @default.
• W2095306247 hasLocation W20953062472 @default.
• W2095306247 hasOpenAccess W2095306247 @default.
• W2095306247 hasPrimaryLocation W20953062471 @default.
• W2095306247 hasRelatedWork W1984919548 @default.
• W2095306247 hasRelatedWork W2059829372 @default.
• W2095306247 hasRelatedWork W2083061825 @default.
• W2095306247 hasRelatedWork W2083546295 @default.
• W2095306247 hasRelatedWork W2095368131 @default.
• W2095306247 hasRelatedWork W2134127756 @default.
• W2095306247 hasRelatedWork W2316070199 @default.
• W2095306247 hasRelatedWork W2793045047 @default.
• W2095306247 hasRelatedWork W2949427009 @default.
• W2095306247 hasRelatedWork W3091916307 @default.
• W2095306247 hasVolume "131" @default.

• next