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• W2095308988 abstract "Icosa­cerium nona­deca­magnesium henocta­conta­zinc, Ce20Mg19Zn81, synthesized by fritting of the pure elements with subsequent arc melting, crystallizes with an unusually large cubic unit cell [space group Foverline{4}3m, a = 21.1979 (8) Å] and represents a new structure type among the technologically important family of ternary rare earth–transition metal–magnesium inter­metallics. The majority of atoms (two Ce and five Zn) display .3m site symmetry, two Ce and one Mg atom occupy three 2.mm positions, one Mg and one Zn have overline{4}3m site symmetry, one Mg and three Zn atoms sit in ..m positions, and one Zn atom is in a general position. The Ce20Mg19Zn81 structure can be described using the geometric concept of nested polyhedral units, by which it consists of four different polyhedral units, viz. A (Zn+Zn4+Zn4+Zn12+Ce6), B (Mg+Zn12+Ce4+Zn24+Ce4), C (Zn4+Zn12+Mg6) and D (Zn4+Zn4+Mg12+Ce6), with the outer construction unit being an octa­hedron or tetra­hedron. All inter­atomic distances in the structure indicate metallic-type bonding." @default.
• W2095308988 created "2016-06-24" @default.
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• W2095308988 date "2008-06-07" @default.
• W2095308988 modified "2023-10-18" @default.
• W2095308988 title "Ce₂₀Mg₁₉Zn₈₁: a new structure type with a giant cubic cell" @default.
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• W2095308988 doi "https://doi.org/10.1107/s0108270108015862" @default.
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• W2095308988 hasPublicationYear "2008" @default.
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